doi: 10.1126/science.290.5489.117.
Xenon as a complex ligand: the tetra xenono Gold(II) cation in AuXe(4)2+(Sb(2)F(11)-)(2)
Affiliations
- PMID: 11021792
- DOI: 10.1126/science.290.5489.117
Item in Clipboard
Xenon as a complex ligand: the tetra xenono Gold(II) cation in AuXe(4)2+(Sb(2)F(11)-)(2)
Science.
.
Abstract
The first metal-xenon compound with direct gold-xenon bonds is achieved by reduction of AuF(3) with elemental xenon. The square planar AuXe(4)2+ cation is established by a single-crystal structure determination, with a gold-xenon bond length of approximately 274 picometers. The bonding between gold and xenon is of the final sigma donor type, resulting in a charge of approximately 0.4 per xenon atom.
Similar articles
-
[XeOXeOXe](2+), the Missing Oxide of Xenon(II); Synthesis, Raman Spectrum, and X-ray Crystal Structure of [XeOXeOXe][μ-F(ReO2F3)2]2.J Am Chem Soc. 2015 Oct 21;137(41):13398-413. doi: 10.1021/jacs.5b08765. Epub 2015 Oct 7. J Am Chem Soc. 2015. PMID: 26394189
-
Synthesis, structural characterization, and computational study of the strong oxidant salt [XeOTeF5][Sb(OTeF5)6].SO2ClF.Inorg Chem. 2005 Jan 10;44(1):49-60. doi: 10.1021/ic0400890. Inorg Chem. 2005. PMID: 15627360
-
X-ray crystal structures of [XeF][MF6] (M = As, Sb, Bi), [XeF][M2F11] (M = Sb, Bi) and estimated thermochemical data and predicted stabilities for noble-gas fluorocation salts using volume-based thermodynamics.Inorg Chem. 2010 Sep 20;49(18):8504-23. doi: 10.1021/ic101152x. Inorg Chem. 2010. PMID: 20735068
-
Xenon Tetrafluoride Molecule and Its Thermal Motion: A Neutron Diffraction Study.Science. 1963 Mar 22;139(3560):1208-9. doi: 10.1126/science.139.3560.1208. Science. 1963. PMID: 17757912
-
Unexpected Trend in Stability of Xe-F Compounds under Pressure Driven by Xe-Xe Covalent Bonds.J Phys Chem Lett. 2016 Nov 17;7(22):4562-4567. doi: 10.1021/acs.jpclett.6b01922. Epub 2016 Nov 1. J Phys Chem Lett. 2016. PMID: 27776206
Cited by
-
Hole interactions of aerogen oxides with Lewis bases: an insight into σ-hole and lone-pair-hole interactions.R Soc Open Sci. 2023 Dec 13;10(12):231362. doi: 10.1098/rsos.231362. eCollection 2023 Dec. R Soc Open Sci. 2023. PMID: 38094266 Free PMC article.
-
Stabilizing Au2+ in a mixed-valence 3D halide perovskite.Nat Chem. 2023 Dec;15(12):1780-1786. doi: 10.1038/s41557-023-01305-y. Epub 2023 Aug 28. Nat Chem. 2023. PMID: 37640854
-
60 years of chemistry of the noble gases.Nature. 2022 Jun;606(7915):659-661. doi: 10.1038/d41586-022-01534-0. Nature. 2022. PMID: 35668186 No abstract available.
-
Reactive p-block cations stabilized by weakly coordinating anions.Chem Soc Rev. 2016 Feb 21;45(4):789-899. doi: 10.1039/c5cs00672d. Epub 2015 Nov 27. Chem Soc Rev. 2016. PMID: 26612538 Free PMC article.
-
Noble Gases in Solid Compounds Show a Rich Display of Chemistry With Enough Pressure.Front Chem. 2020 Nov 5;8:570492. doi: 10.3389/fchem.2020.570492. eCollection 2020. Front Chem. 2020. PMID: 33251181 Free PMC article. Review.
LinkOut - more resources
Full Text Sources
