doi: 10.1002/chem.200901472.
Molecular double-bond covalent radii for elements Li-E112
Affiliations
- PMID: 19856342
- DOI: 10.1002/chem.200901472
Item in Clipboard
Molecular double-bond covalent radii for elements Li-E112
Chemistry.
.
Abstract
The previous systems of triple-bond and single-bond self-consistent, additive covalent radii, R(AB)=r(A)+ r(B), are completed with a fit for sigma(2)pi(2) double-bonds.The primary bond lengths, R, are taken from experimental or theoretical data corresponding to chosen group valencies. All r(E) values are obtained from the same, self-consistent fit. Many of the calculated primary data came from E=CH(2) and H-E=CH(2) models. Homonuclear LE=EL, formaldehyde-type Group 14-Group 16 and open-shell, X (3) Sigma Group-16 dimer data are included. The standard deviation for the 316 included data points is 3 pm.
Similar articles
-
Molecular single-bond covalent radii for elements 1-118.Chemistry. 2009;15(1):186-97. doi: 10.1002/chem.200800987. Chemistry. 2009. PMID: 19058281
-
Triple-bond covalent radii.Chemistry. 2005 Jun 6;11(12):3511-20. doi: 10.1002/chem.200401299. Chemistry. 2005. PMID: 15832398
-
Direct estimate of the strength of conjugation and hyperconjugation by the energy decomposition analysis method.Chemistry. 2006 Apr 24;12(13):3617-29. doi: 10.1002/chem.200501405. Chemistry. 2006. PMID: 16502455
-
Linear M[triple bond]E-Me versus bent M-E-Me: bonding analysis in heavier metal-ylidyne complexes [(Cp)(CO)2M[triple bond]EMe] and metallo-ylidenes [(Cp)(CO)3M-EMe] (M = Cr, Mo, W; E = Si, Ge, Sn, Pb).Inorg Chem. 2009 Apr 6;48(7):2748-59. doi: 10.1021/ic801072g. Inorg Chem. 2009. PMID: 19256519
-
Accounting for the differences in the structures and relative energies of the highly homoatomic np pi-np pi (n > or = 3)-bonded S2I4 2+, the Se-I pi-bonded Se2I4 2+, and their higher-energy isomers by AIM, MO, NBO, and VB methodologies.Inorg Chem. 2007 Feb 5;46(3):681-99. doi: 10.1021/ic061523w. Inorg Chem. 2007. PMID: 17257010
Cited by
-
BN isosteres of indole.Org Biomol Chem. 2013 Apr 7;11(13):2060-9. doi: 10.1039/c3ob27436e. Org Biomol Chem. 2013. PMID: 23403937 Free PMC article. Review.
-
Coordination-induced polymerization of P═C bonds leads to regular (P─C) n polycarbophosphanes.Sci Adv. 2021 Mar 10;7(11):eabf4272. doi: 10.1126/sciadv.abf4272. Print 2021 Mar. Sci Adv. 2021. PMID: 33692112 Free PMC article.
-
Crown-like charge-transfer lithium-doped boron oxide complexes B8O2Li+/0.J Mol Model. 2019 Dec 26;26(1):18. doi: 10.1007/s00894-019-4280-4. J Mol Model. 2019. PMID: 31879806
-
Probing the Fluxional Bonding Nature of Rapid Cope rearrangements in Bullvalene C10H10 and Its Analogs C8H8, C9H10, and C8BH9.Sci Rep. 2019 Nov 19;9(1):17074. doi: 10.1038/s41598-019-53488-5. Sci Rep. 2019. PMID: 31745136 Free PMC article.
-
Halogenation and Nucleophilic Quenching: Two Routes to E-X Bond Formation in Cobalt Triple-Decker Complexes (E=As, P; X=F, Cl, Br, I).Chemistry. 2022 Aug 1;28(43):e202201026. doi: 10.1002/chem.202201026. Epub 2022 Jun 14. Chemistry. 2022. PMID: 35575044 Free PMC article.
LinkOut - more resources
Full Text Sources
Other Literature Sources
Research Materials
Miscellaneous
